Construction of manganese-based metal organic frameworks derived from aromatic dicarboxylic acids and application for the adsorption of iodine

Abstract

In this work, we selected terephthalic acid or 2-amino-terephthalic acid as ligand, transition metal manganese salt as metal source under the solvothermal conditions to successfully construct two kinds of manganese-based metal-organic frameworks (Mn-MOFs): Mn3(BDC)3(H2O)2 (1) and Mn3(NH2-BDC)3(DMF)4 (2) (H2BDC = terephthalic acid; NH2-BDC = 2-amino terephthalic acid; DMF = N, N-dimethyl formamide). It was characterized by elemental analysis, IR spectrum, thermogravimetric analysis (TG), X-ray powder diffraction (PXRD) and UV-vis absorption spectrum. It was found that the packing structures of compounds 1 and 2 were constructed by the trinuclear Mn3O16 building block and exhibited different spatial structure: compound 1 was a three-dimensional structure, and 2 was a two-dimensional network structure. The iodine adsorption in cyclohexane solution properties of compounds 1 and 2 were investigated. Research results showed that the uncoordinated amino group in the structure of framework compounds has a great influence on the iodine adsorption capacity and compound 2 had good adsorption property and reusability.