Abstract
Self-assembly of CuX2 (X− = Cl− and Br−) with a new tridentate ligand, N,N′,N′′-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide (L), yields a uniquely very thin kagome-type network consisting of both nano-sized hexagonal (Cu6L6) and triangular (Cu3L3) motifs with the former as an effective reservoir for small alcohol molecules.
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