Abstract
The addition of a variety of the highly functionalized zinc–copper reagents RCu(CN)ZnI to the title cation gives (η6-cyclohepta-1,3,5-triene)Cr(CO)3 complexes with a functionalized side chain at the C-7 position of the ring: intramolecular cyclisation of ester-substituted adducts using lithium diisopropylamide generates fused bicyclo-[5.3.0]decane and -[5.4.0]undecane derivatives.
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