Construction of electrospinning Janus nanofiber membranes for efficient solar-driven membrane distillation

Abstract

Low permeate flux and membrane fouling are major limiting factors for solar-driven membrane distillation (SDMD) industrial applications. Here, we report a Janus nanofiber membrane with electrospinning CB/PVA as hydrophilic photothermal layer and electro-blown spinning PTFE nanofiber membrane as hydrophobic layer, which exhibits excellent photothermal conversion performance, anti-fouling performance and durability. The hydrophilic photothermal layer simultaneously captures solar energy and performs photothermal conversion, repels chemical/oil-based pollutants and promotes steam flow. At the same time, the low surface of PTFE layer can guarantee the long-term durability of the composite nanofiber membrane. Under the light intensity of 1 kW·m−2, the Janus nanofiber membrane can obtain a permeate flux of 1.05 L·m−2·h−1 and a salt rejection of > 99.99 %. And the photothermal conversion efficiency reached 71.4 %. More importantly, the permeate flux of the Janus nanofiber membrane was still stable at 1.035 L·m−2·h−1 after continuous treatment of pollutant-containing feed solutions for 60 h, and the salt rejection was > 99.98 %. This indicates that the efficient photothermal conversion performance and anti-fouling properties make the CB-PVA/PTFE photothermal nanofiber membrane promising for generating fresh water from feed solutions containing various pollutants in SDMD systems.