Construction of Carboxymethyl Chitosan Hydrogel with Multiple Cross-linking Networks for Electronic Devices at Low Temperature.

Abstract

On the basis of the original hydrogen bonding interaction and physical entanglement, covalent cross-linking and ionic cross-linking were additionally introduced to construct a carboxymethyl chitosan/allyl glycidyl ether conductive hydrogel (CCH) through a one pot method by a graft reaction, an addition reaction, and simple immersion, successively. The multiple cross-linking networks significantly increased the strength of CCHs and endowed them with ionic conductivity and an antifreezing property at -40 °C, which showed stable, durable, and reversible sensitivity to finger bending activity at subzero temperature. The CCHs could even be assembled into a triboelectric nanogenerator (TENG) to provide electric energy, which demonstrated stability against temperature variation, multiple drawing, long-term storage, or large quantities of contact-separation motion cycles. CCH-TENG can also be used as a tactile sensor within the pressure range from 0.4 kPa to higher than 8000 kPa. This work provided a simple route to fabricate antifreezing conductive hydrogels based on carboxymethyl chitosan and to find potential applications in soft sensor devices under a low temperature environment.