Construction of carbon nitride/zeolitic imidazolate framework-67 heterojunctions on carbon fiber cloth as the photocatalyst for various pollutants removal and hydrogen production

Abstract

With the macroscale and conductive carbon fiber cloth (CFC) as the substrate, the obtained self-supported photocatalysts hold great promise for enhancing the separation of generated carriers and the recyclability of catalysts, thereby improving the photocatalytic performance and practicality in various applications. Additionally, decorating metal–organic frameworks (MOFs) with ultrahigh surface area on the surface of effective semiconductors is a promising method to enhance the adsorption capacity and photocatalytic performance. Herein, zeolitic imidazolate framework-67 (ZIF-67) as a typical MOFs was applied to modify carbon nitride (C3N4) on the surface of macroscale and conductive CFC. CFC/C3N4/ZIF-67 (4 × 4 cm2) was obtained by a thermal condensation-chemical bath deposition two-step route, and it shows superior adsorption and photocatalytic activity toward bisphenol A (BPA), levofloxacin (LVFX), ciprofloxacin (CIP) and good hydrogen evolution activity. Besides, the recycling test for four cycles indicates the high stability of CFC/C3N4/ZIF-67 with an easy recycling process. In this study, CFC/C3N4/ZIF-67 was prepared through the hydrothermal and chemical bath deposition two-step method, which enhances light absorption and photocatalytic performance, as well as recyclability for solving environmental and energy issues.