Construction of carbon-doped mesoporous g-C3N4 catalytic nanoreactor via bubble template method for visible-light photocatalysis

Abstract

Morphological control of photocatalysts is an important way to improve photocatalytic activity. Herein, we design a carbon-doped mesoporous g-C3N4 nanoreactor by combining the self-assembly method of supramolecular precursors with the bubble template method. The mesoporous structure can increase the utilization rate of light absorption. Furthermore, the C atoms replace the position of bridging N atoms may generate delocalized large π bonds, both of which can facilitate photocatalysis. This nanoreactor coupled with larger specific surface area and faster electronic transmission efficiency shows an outstanding performance in photocatalytic RhB degradation (97%, 15 min) and reducing CO2 into CO (60.82 μmol/g, 5h). The C-doped mesoporous g-C3N4 nanoreactor would provide some practical reference for environmental improvements and clean energy production.