Abstract

A 3d–4f heterometallic coordination polymer, {[Cu 10Er 4(IN) 14ClBr 7(H 2O) 10] · 2H 2O} n ( 1) [IN = isonicotinate], has been synthesized by hydrothermal reaction of the ligand with CuBr 2, NaCl and Er 2O 3. Complex 1 represents a rare 3D heterometallic coordination framework constructed from Er-carboxylate subunits and unique Cu-halide (Br/Cl) chains that are bridged by a single type of linear ligand. Furthermore, the luminescent properties of complex 1 have also been investigated.

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