Abstract
Two new coordination polymers, {[Pb(μ2-H2TFMIDC)2-(μ2-H2O)]·H2O}n (H3TFMIDC=2-(trifluoromethyl)-4,5-imidazole dicarboxylic acid, 1) and [Ba(μ2-H2TFMIDC)(μ4-H2TFMIDC)(H2O)]n (2), were constructed under hydrothermal/solvothermal conditions. Compound 1 is an achiral 3D framework based on irregular helical chains and displays a 6-connected pcu network topology. Compound 2 exhibits a 3D chiral framework based on homochiral 1D helical chains with a (4,8)-connected network topology. The luminescence properties of compounds 1–2 were also investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
