Abstract
The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4{\bar 4}04 are presented. The performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s−13d−1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.
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