Abstract

HighlightsA scalable tape-casting method produces self-supported porous Li6.4La3Zr1.4Ta0.6O12.Combining the in-situ polymerization approach, a composite solid electrolyte with superior electrochemical properties is fabricated.Solid-state Li|CSE|LiNi0.8Co0.1Mn0.1O2 cells show remarkable cyclability and rate capability.LiF-and B-rich interphase layers mitigate interfacial reactions, enhancing solid-state battery performance.

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