Abstract
Starting from a dinuclear complex {Gd2(L)2(NO3)4(H2O)2}·2(CH3CN) (1) based on 2,6-dimethoxyphenol (HL), a nonanuclear cluster {Gd9(L)4(μ4-OH)2(μ3-OH)8(μ2-OCH3)4(NO3)8 (H2O)8}(OH)·2H2O (2) was obtained via modulating the amount of the ligand and base. Both of them have been structurally and magnetically characterized. Complex 1 decorates the Gd2 core bridged by double μ2-phenoxyl oxygen atoms and coordinated neutral CH3CN molecules, while 2 features the Gd9 core with a sandglass-like topology. Magnetic investigations reveal that the weaker antiferromagnetic interactions between adjacent metal ions exist in complex 2 than in 1, which is in agreement with the theoretical results. Meanwhile, the magnetocaloric effect with a maximum -ΔS m value changes from 27.32 to 40.60 J kg-1 K-1 at 2 K and 7 T.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
