Construction of a Hierarchical Structure of Bimetallic Oxide Derived from Metal-Organic Frameworks.

Abstract

Bimetallic oxides are a class of promising advanced functional metal nanomaterials, especially in terms of the sophisticated hierarchical structure of bimetallic oxide, which not only is in favor of enhancing their intrinsic physiochemical properties because of more accessible actives sites but also is capable of integrating the synergistic effect between two metals. Herein, we report a novel strategy to controllably construct bimetallic CuO/ZnO nanomaterials with sophisticated hierarchical structure through a pseudomorphic transformation and subsequent calcination process. The resulting unique hierarchical structure of ZnO/CuO is primarily constituted of a nanosphere and a rod grafted in a microscale cube with multidimensional size, which thus results in excellent dispersion, superior charge-transport capability, and abundant accessible active sites. Impressively, the optimized hierarchical structure product of CuO/ZnO (4:1) demonstrates an excellent glucose detection performance with a rapid response time, a wide linear range, a low detection limit, and strong antiinterference ability, realizing more advantages than commercial CuO or ZnO materials and shedding light on the positive correlation of the structure and performance. This study provides a new strategy for the controllable fabrication of the sophisticated hierarchical structure of bimetallic oxide nanomaterials.