Abstract
Abstract A novel ammonium template containing three ammonium sites was synthesized. Two ammoniums located on the linear component served as template for cucurbit[6]uril to form the CB-based pseudo [2]rotacane while another one located on the macrocyclic component played a role of template for clipping reaction. As a result of a “threading-followed-by-clipping” approach, a novel hetero pseudo [2]rota[2]catenane was successfully constructed.
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