Construction of α-MnO2/g-C3N4 Z-scheme heterojunction for photothermal synergistic catalytic decomposition of formaldehyde

Abstract

Formaldehyde (HCHO), as the most common indoor air pollutant, undoubtedly poses a huge threat to people's health. It is of practical importance to achieve complete decomposition of HCHO to harmless CO2 at room temperature. Herein, α-MnO2/g-C3N4 Z-scheme heterojunction was constructed through the in-situ growth of α-MnO2 nanowires on the surface of g-C3N4 nanosheets. Owing to the construction of Z-scheme heterojunction, α-MnO2/g-C3N4 composite exhibits excellent photothermal catalytic activity, achieving complete mineralization of HCHO with the illumination of 191 mW/cm2 solar-light at GHSV of 180 L/gcat·h. Particularly, even under one sun and visible light radiation, the α-MnO2/g-C3N4 composite can still maintain 60% and 68% HCHO conversion, respectively. The formation of α-MnO2/g-C3N4 Z-scheme heterojunction not only effectively inhibits the photogenerated electron-hole pairs recombination, but also overcomes the band defects of the individual component. Furthermore, the mechanism of the photothermal catalysis of α-MnO2/g-C3N4 composite was discovered to be thermal-assisted photocatalytic process rather than solar-light driven thermalcatalysis. On the one hand, the thermal energy generated from light radiation can accelerate the migration of photo-generated carriers and improve the separation efficiency of photogenerated electrons from vacancies; on the other hand, it can decrease the activation energy of lattice oxygen and produce more surface-active oxygen species. This work provides cost-effective strategies and suggestions for decomposing HCHO and other VOCs in indoor air at room temperature.