Constructing three-dimensional network C, O Co-doped nitrogen-deficient carbon nitride regulated by acrylic fluoroboron overall marine antifouling

Abstract

To deal with unwanted biofouling adsorption, which impacts the economy and the environment, significant research has been devoted to composite systems involving a photocatalyst combined with self-renewal resin to provide synergistic antifouling. Here, photocatalyst based on three-dimensional (3D) network of carbon–oxygen-doped nitrogen-deficient carbon nitride and acrylic fluoroboron polymer as a system was successfully synthesized. 3D networks carbon nitride with carbon–oxygen dopants and nitrogen defects were prepared as skeletons, which effectively support and regulate the hydrolysis rate of the polymer. These composite systems exhibits excellent diatom anti-adhesion performance and high antibacterial rates for Escherichia coli and Staphylococcus aureus of up to 91.87% and 88.52%, respectively. In addition, self-cleaning function of the composite system are proved by and higher efficiency of chemical oxygen demand (COD) removal owing to efficient charge-carrier separation and transfer within the 3D network carbon nitride network. The great potential applications of this strategy demonstrated in marine engineering in the future.