Constructing liquid metal/metal-organic framework nanohybrids with strong sonochemical energy storage performance for enhanced pollutants removal

Abstract

With endogenous redox systems and multiple enzymes, the storage and utilization of external energy is general in living cells, especially through photo/ultrasonic synthesis/catalysis due to in-situ generation of abundant reactive oxygen species (ROS). However, in artificial systems, because of extreme cavitation surroundings, ultrashort lifetime and increased diffusion distance, sonochemical energy is rapidly dissipated via electron-hole pairs recombination and ROS termination. Here, we integrate zeolitic imidazolate framework-90 (ZIF-90) and liquid metal (LM) with opposite charges by convenient sonosynthesis, and the resultant nanohybrid (LMND@ZIF-90) can efficiently capture sonogenerated holes and electrons, and thus suppress electron-hole pairs recombination. Unexpectedly, LMND@ZIF-90 can store the ultrasonic energy for over ten days and exhibit acid-responsive release to trigger persistent generation of various ROS including superoxide (O2•−), hydroxyl radicals (•OH), and singlet oxygen (1O2), presenting significantly faster dye degradation rate (short to seconds) than previously reported sonocatalysts. Moreover, unique properties of gallium could additionally facilitate heavy metals removal through galvanic replacement and alloying. In summary, the LM/MOF nanohybrid constructed here demonstrates strong capacity for storing sonochemical energy as long-lived ROS, enabling enhanced water decontamination without energy input.