Constructing Artificial Light-Harvesting Systems by Covalent Alignment of Aggregation-Induced Emission Molecules.

Abstract

The characteristics of chloroplasts harvesting solar energy and conducting energy transfer have inspired chemists to mimic similar processes. However, accurate manipulation to gain regularly displayed antenna chromophores in mimicking chloroplasts is a great challenge. Herein, a rational design is presented that combines orderly arranged chromophores with aggregation-induced emission (AIE) to develop artificial light-harvesting systems. Tetraphenyl ethylene (TPE) molecules, which exhibited strong AIE properties, are considered as building blocks to fabricate high emissive 2D nanosheets and nanovesicles, respectively. Furthermore, the well-aligned TPE molecules are also developed as donor chromophores in light-harvesting processes. After subsequent surface modification by porphyrin molecules as acceptor chromophores, an efficient light-harvesting system has been integrally constructed. This study demonstrates a novel strategy to utilize AIE feature to mimic chloroplasts process in nature.