Constructing amphipathic molecular layer to assists de-solvation process for dendrite-free Zn anode

Abstract

Due to the excellent safety feature, substantial theoretical capacity and abundant zinc reserves in the earth's crust, Aqueous Zn-ion batteries (AZIBs) are promising as the next generation energy storage system. However, the problem of dendrite growth and the related side reactions in Zn surface limit their further development and application. Herein, an amphipathic molecular layer (Polyacrylic Acid, named as PAA) is constructed on Zn surface to hinder the side reactions and zinc dendrites by intervening the de-solvation process. It is found that the rich hydroxyl group in polyacrylic acid is very hydrophilic. On the contrary, hydrocarbon group on the other side is nearly hydrophobic. The amphiphilic PAA molecular layer on Zn surface results in lower de-solvation energy barrier, thus inhibits the decomposition of water and related side reactions. Additionally, the accumulate abundant negative charge at the interface of polyacrylic acid and Zn surface can attract homogeneous deposition of Zn atoms. Using only 0.01 M PAA as additive in 2.0 M ZnSO4 electrolyte. Zn||Zn symmetric cells expresses a superior cycling stability of 4643 h (5 mA cm−2, 1 mAh cm−2). This study provides new insights into the long-life AZIBs modulated by amphipathic molecular layer.