Constraining Trifluoromethane (HFC‐23) Emission in Eastern China Based on Two‐Year Online Measurements

Abstract

AbstractTrifluoromethane (CHF3, HFC‐23) is one of the most potent greenhouse gases (GHGs), and eastern China has been recognized as a major source region, yet highly inconsistent emission estimates warrant more extensive studies. In this study, we conducted 2‐year online measurements of halocarbons during 2021–2023 at an urban site in the Pearl River Delta region. The observed average HFC‐23 mixing ratios of 43.6 ± 7.8 ppt were ∼20% enhanced compared to observations at the Mace Head global baseline station. Unlike other halocarbons with significant local emissions, HFC‐23 mixing ratios showed distinct seasonal variations with peak values in winter and bottom values in summer. Similar seasonal patterns and highly significant correlation were observed between HFC‐23 and perfluorocyclobutane (c‐C4F8, PFC‐318), a co‐product from manufacturing PTFE using chlorodifluoromethane (CHClF2, HCFC‐22) as feedstock. The weighted potential source contribution function analysis also demonstrated eastern China was the major source area for both HFC‐23 and PFC‐318. Tracer‐based estimation revealed HFC‐23 emissions of 6.7 ± 3.1 Gg yr−1 (equivalent to 98 Tg‐CO2 yr−1 or 0.7% China's annual GHG emissions in 2021) in eastern China. Our results highlight the importance of HFC‐23 emission control in eastern China for China's GHG and F‐gases emission reductions, and suggest that greater attention should be given to HFC‐23 emissions from PTFE production, which is emerging as a more substantial source than previously anticipated.