Abstract
Reaction of 1-(2- N, N-dimethylaminophenyl)-2-methylindenyllithium with (Ph 3P) 3RuCl 2 affords the chloro(indenyl)bis(triphenylphosphine)ruthenium(II) complex 5, where the nitrogen is not coordinated to the metal. The corresponding reaction of 1-(2- N, N-dimethylamino-6-methylphenyl)-2-methylindenyllithium affords the chloro(η 5:κ N-indenyl)(triphenylphosphine)ruthenium(II) complex 6, which has been characterised by single crystal X-ray analysis.
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