Constrained coordination through atropisomerism: Synthesis and structure of an η 5:κ N-bidentate N, N-dimethylaniline-functionalised indenylruthenium(II) complex

Robert W Baker,Ian J Luck,Peter Turner

doi:10.1016/j.inoche.2005.06.002

Constrained coordination through atropisomerism: Synthesis and structure of an η 5:κ N-bidentate N, N-dimethylaniline-functionalised indenylruthenium(II) complex

Robert W Baker, Ian J Luck + Show 1 more

https://doi.org/10.1016/j.inoche.2005.06.002

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Journal: Inorganic Chemistry Communications	Publication Date: Jul 20, 2005
Citations: 5

Affiliation: University of Sydney

#Indenylruthenium #Ph 3P + Show 2 more

Abstract
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Abstract

Reaction of 1-(2- N, N-dimethylaminophenyl)-2-methylindenyllithium with (Ph 3P) 3RuCl 2 affords the chloro(indenyl)bis(triphenylphosphine)ruthenium(II) complex 5, where the nitrogen is not coordinated to the metal. The corresponding reaction of 1-(2- N, N-dimethylamino-6-methylphenyl)-2-methylindenyllithium affords the chloro(η 5:κ N-indenyl)(triphenylphosphine)ruthenium(II) complex 6, which has been characterised by single crystal X-ray analysis.

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