Abstract

IN a former publication1, the changes in the distribution of intensity of the Raman band of water with temperature have been explained on the hypothesis that water consists of three types of molecules, single (H2O), double (H2O)2 and triple (H2O)3, as revealed by the presence of three components in the band. Since these components were mixed up, it was not then possible to analyse the band to estimate quantitatively their relative intensities, for the determination of the proportions of these three types of molecules. Further work with ice and water at 0°, 4°, 38°, and 98°C. has now made such an analysis possible.

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