Abstract
Problems that arise in refining calculations of the equilibrium thermodynamic functions of an adsorbate located near an adsorbent’s surface or inside slit-like pores when its collective vibrational motions are considered are discussed. A technique is proposed for calculating collective vibrations for a small number of vacancies in a defective heterogeneous adsorbate from changes in the number of degrees of freedom and the local frequencies in the frequency distribution function in an ideal bulk crystal.
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