Abstract
The second-order connected moments expansion (CMX(2)) approach to calculation of the correlation energy is tested numerically on several closed-shell di- and tri-atomic molecules. Benchmark computations performed within 6–31G ∗∗ basis set reveal that CMX(2) usually recovers more than 50% of the MP3 correlation energy and improves the SCF molecular geometries at a cost comparable to the MP3 calculations.
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