Conjugated Polymer Nanoparticles Based on Anthracene and Tetraphenylethene for Nitroaromatics Detection in Aqueous Phase

Abstract

The sensitive and selective detection of nitroaromatic explosives is of great significance to national security and human health. Herein, the novel linear polymer l-PAnTPE and cross-linked polymer PAnTPE nanoparticles based on anthracene and tetraphenylethene groups were designed and successfully synthesized via Suzuki-miniemulsion polymerization. The particle sizes of the polymers are around 73 nm, making them well dispersible in water. The cross-linked polymer PAnTPE exhibits porous structure, which is beneficial for the diffusion/adsorption of analytes. The fluorescence sensing towards nitroaromatics was performed in the aqueous phase, and l-PAnTPE and PAnTPE nanoparticles showed different quenching degree towards different nitroaromatics. Among them, the quenching constant KSV values of l-PAnTPE and PAnTPE towards 2,4,6-trinitrophenol (TNP) reach 1.8 × 104 M−1 and 4.0 × 104 M−1, respectively, which are 1–2 orders of magnitude higher than other nitroaromatic explosives, thus demonstrating the high sensitivity and selectivity of TNP detection in the aqueous phase. The sensing mechanism was further discussed to clarify this phenomenon by analyzing UV–Vis absorption, excitation, fluorescence spectra, cyclic voltammograms and fluorescence decay measurements. In addition, the paper strips tests exhibit that l-PAnTPE and PAnTPE have great potential in the application of fast, low-cost and on-site nitroaromatics detection.