Congener profiles and process distributions of polychlorinated biphenyls, polychlorinated naphthalenes and chlorinated polycyclic aromatic hydrocarbons from secondary copper smelting

Abstract

Secondary copper smelting is an important industrial source of unintentionally produced persistent organic pollutants (UPOPs) emissions. Herein, field study on industrial-scale plants was conducted to clarify the levels and profiles of polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs) and chlorinated polycyclic aromatic hydrocarbons (> 3 rings, Cl-PAHs) from secondary copper smelting plants. The three UPOPs emission levels from the oxygen-enriched smelting furnace were higher than that from the anode furnace, which was attributed to the low-grade raw materials used. The toxic equivalent quantity concentrations of Cl-PAHs were 1.3–4.4 and 4.6–18.9 times higher than that of PCBs and PCNs, respectively. Thus, the emission control of Cl-PAHs in the secondary copper industry should be of concern. The chlorination degree of PCBs and PCNs was ~4 after the gas-cooling stage but was reduced to 1–2 in the stack outlet. This result indicated that the PCBs and PCNs congeners that were generated during the cooling stage were mainly higher-chlorinated. After purification by air pollution control devices (APCDs), the high-chlorinated congeners were removed simultaneously with the fly ash, whereas the low-chlorinated congeners may be regenerated and transferred into the stack gas due to possible memory effect within the APCDs.