Abstract
The conformations and motions of polypropylene (PP) chains isolated in the narrow channels (D=5.5 A) of their inclusion compounds with perhydrotriphenylene (PHTP) are modeled. PP's are treated with various stereosequences and it is found that: (i) neither stereoregular PP [isotatic (i) or syndiotactic (s)] can adopt its crystalline conformation in the PHTP channels; (ii) interconversion between channel conformers is not possible; and (iii) the channel conformers of s-PP have a much lower intramolecular energy than the channel conformers of i-PP
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
