Abstract

Internal stresses in glassy polymer materials arise from two different sources; deviation of polymer conformation from its equilibrium state and change of intersegment distances. These stress components may be separately observed by carrying out simultaneous measurements of tensile stress and birefringence relaxations of polymer films, assuming that they are additive. It is pointed out that the change of intersegment distances occurs first, and conformational deformation is gradually induced if a glassy polymer film is elongated

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