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Abstract
The position of conformational equilibria in 2- and 3-methyl-1,4-thiazanes and cis- and trans-2,3-dimethyl-1,4-thiazanes, their N-methyl derivatives, and several of the correSponding sulfoxides and sulfones have been measured. The ΔG o values for the methyl groups are generally in agreement with what one would expect on the basis of known conformational equilibria in methylthianes, methylpiperidines, and N-methylated homologs of the latter; however, the differences in ΔG o between the 2-methyl and N,2-dimethyl homologs are even larger than in the piperidine series
Published Version
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