Abstract
The photoelectron spectra of 2-haloethanols and 2-methoxyethylhalides have been interpreted by “ab initio” calculations. The results support the hypothesis that, in vapor phase, fluoride and chloride derivatives exist only in one rotameric form: the gauche form for the alcohols and the planar trans form for the ethers. In case of bromo and iodo compounds both forms coexist.
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