Abstract
Two general methods of conformational analysis by kinetic methods are distinguished, and some definitive experiments are described concerning the validity of the reactivity-model method as employed for cyclohexanes. The fast chemical reaction method is analysed in detail, and potential applications to conformational equilibria of N-alkylpiperidines are discussed. The selectivity of electrophilic addition of some photogenerated carbenes and nitrenes to organic sulphides is examined.
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