Abstract
Reported here are measurements of the rotational spectra of two isotopologues ( 35Cl and 37Cl) of one of the simplest chiral carboxylic acids, 2-chloropropionic acid. The spectra have been obtained in a supersonic expansion, using free-jet millimeter-wave direct-absorption as well as pulsed-jet FT microwave spectroscopies. A single conformer has been detected, characterized by a methyl group nearly cis with respect to the carbonylic oxygen. Within the realm of chiral recognition, the relative simplicity of the observed spectrum should allow for the detection of the microwave spectrum of the polar homo-dimer.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.