Abstract
A relationship was found between the γ-effect values in 13C NMR spectra and the solution conformation of the title compounds. Base-catalyzed equilibration of anancomeric 2-phosphoryl and 2-thiophosphoryl substituted 5-t-butyl-1,3-dithianes showed that axial preference increases in the order: Ph 2P(S)<Ph 2P(O)<(MeO) 2P(O). Explanation of this phenomenon is proposed, based also on the results of molecular mechanics calculations.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
