Abstract
Abstract A novel catalytic system was developed through confinement of TEMPO task-specific ionic liquid (TEMPO-IL) with CuCl 2 in a silica-gel matrix by sol-gel technique. The obtained TEMPO-IL/CuCl 2 /silica-gel catalytic system was effective for the transformation of a series of benzylic, allylic and heterocyclic alcohols to the respective carbonyl compounds under O 2 atmosphere. Notably, the system facilitates ease separation of the catalyst and product and shows good reusability in the reaction.
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