Confined PbO2 nanoparticles in carbon nanotubes on boron-doped diamond substrate for highly efficient chlortetracycline degradation

Abstract

Realizing highly efficient catalysis with high stability in complex chemical environments remains a major challenge for advanced oxidation processes. Here, confined lead dioxide (PbO2) nanoparticles in carbon nanotubes (CNTs) on boron-doped diamond (BDD) substrate is designed and fabricated as a heterogeneous catalyst for antibiotic treatment, achieving ultra-efficient degradation of chlortetracycline (CTC) with high reaction rate and stability. The maximum degradation rate of CTC reaches 98.8 % in 120 min, and it remains 91.0 % after ten cycles, which are significantly higher than that proposed by the contrast catalysts. The excellent degradation performance of this heterogeneous catalyst is mainly attributed to three factors: (i) the prepared PbO2 nanoparticles with an average size of 5 nm are confined in CNTs, providing more active sites and higher electron transfer rate; (ii) secondary pollution and catalyst deactivation of PbO2 are avoided by protecting CNTs; (iii) BDD shows strong capacity for mineralizing organic compounds related to the high oxygen evolution reaction potential. This finding provides a novel strategy for advanced oxidation processes in environmental remediation.