Abstract
The cover picture shows the left-handed (M) and the right-handed (P) propeller conformations of a stable tris(tetrathioaryl)methyl radical and its isomerization mechanism. Due to steric hindrance, enantiomerization between the two chiral conformations (M and P) of tris(tetrathioaryl)methyl radicals, alcohols and alkanes is restricted allowing isolation of enantiomers. Details of this work are described in the article by J. Marchand-Brynaert et al. on p. 6517 ff.
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