Abstract
Abstract The electric conductivity of NaCl and NaI in water — 2-butoxyethanol mixtures was measured at 298.15K and analysed using Fuoss — Justice equation. For the both salts, the limiting molar conductance decreases and the equilibrium constant of ion-pair formation increases along with increase of 2-butoxyethanol content. The standard dissolution enthalpies of NaCl and NaI in water — 2-butoxyethanol mixtures were recalculated taking into account the ion — association process. The electric permittivity for mixtures of water with 2-butoxyethanol was measured over the whole composition range within 288.15 – 308.15K. The Kirkwood correlation factor for investigated mixtures was calculated.
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