Conductivity studies of plasticized proton conducting PVA–PVIM blend doped with NH4BF4

Abstract

The proton conducting solid-state polymer electrolyte comprising blend of poly(vinyl alcohol) (PVA) and poly(N-vinylimidazole) (PVIM), ammonium tetrafluoroborate (NH4BF4) as salt, and polyethylene glycol (PEG) (molecular weight 300 and 600) as plasticizer is prepared at various compositions by solution cast technique. The prepared films are characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, X-ray diffraction, and scanning electron microscopy analysis. The conductivity–temperature plots are found to follow an Arrhenius nature. The conductivity of solid polymer electrolytes is found to depend on salt and plasticizer content and also on the dielectric constant value and molecular weight of the plasticizer. Maximum ionic conductivity values of 2.20 × 10−4 and 1.28 × 10−4 S cm−1 at 30 °C are obtained for the system (PVA–PVIM) + 20 wt.% NH4BF4 + 150 wt.% PEG300 and (PVA–PVIM) + 20 wt.% NH4BF4 + 150 wt.% PEG300, respectively. The blended polymer, complexed with salt and plasticizer, is shown to be a predominantly ionic conductor. The proton transport in the system may be expected to follow Grotthuss-type mechanism.