Abstract
A solid solution Pb 1−xSb xF 2+x (0 < x ≤ 0.40) of fluorite type and a definite Pb 2Sb 3F 13 phase have been obtained at 250°C in the PbF 2|SbF 3 system. The study of the variation of the ionic conduction shows that Pb 0.75Sb 0.25F 2.25 is a good ionic conductor.
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