Abstract

New mono-functionalised, amphiphilic tetrathiafulvalene (TTF) derivatives have been synthesised and shown to form Langmuir-Blodgettt films, some of which are semiconducting ( δ rt = 10 −5-10 −2Scm −1 after iodine doping. These layers have been characterised by UV-Visible and IR spectroscopy in the undoped and doped states. X-ray crystal structures of related TTF derivatives substituted with a thioester and a thioamide group are presented.

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