Abstract
The electrical conductances of solutions of sodium chloride (NaCl), potassium chloride (KCl), sodium bromide (NaBr), sodium iodide (NaI), sodium tetraphenylborate (NaBPh4), and tetrabutylammonium iodide (Bu4NI) in water (1) + 2-ethoxyethanol (2) mixtures containing (0.01, 0.025, 0.05, 0.075, 0.10, 0.15, and 0.20) mol fractions of 2-ethoxyethanol have been measured at 298.15 K. The conductance data have been analyzed by the Fuoss−Justice equation. The individual limiting ionic conductivities of Na+, K+, Bu4N+, BPh4−, I−, Cl−, and Br− ions have been determined using the Fuoss−Hirsch assumption. The dependencies of the limiting molar conductances, Λo, and Walden products, Λoη, versus mixed solvent composition have been discussed.
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