Abstract
In accordance with the theory of vibrational relaxation, a rare gas halide (RgX) excimer or similar electronically excited molecule cannot be characterized by one universal set of kinetic parameters. Both the quenching rate constants and the effective radiative lifetimes are discovered to depend on the internal energy of generated molecules and gaseous-mixture composition. It is emphasized that different values of a kinetic parameter have to be used under steady-state and pulse conditions.
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