Abstract

The reaction of o-phenylene diamine with Β-alkoxy-, Β-dimethylamino-, and Β-acetoxy-α-alkyl- or α-arylacroleins has been studied. A new synthesis of 7,16-diaryl[5,14]dihydro[b,i]dibenzo-[5,9,14,18]tetraaza[14]annulenes was developed, and the syntheses of 5,14-dihydro[b,i]dibenzo[5,9,14,18]tetraaza-[14]annulene and 7,16-dialkyl[5,14]dihydro[b,i]dibenzo[5,9,14,18]tetraaza[14]-annulenes were improved. 5,14-Dihydro[b,i]dibenzo[5,9,14,18]tetraaza[14]-annulenes were synthesized with various substituents in the benzene rings and at positions 7 and 16.

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