Abstract
The purposeful synthesis of polyfunctional organic substances is an important task in organic chemistry, as well as for solving practical problems in technologies of fine organic chemistry and biochemistry. Here presents the results of studies on the synthesis of polyfunctional substances as possible ligand based on with malonic acid diethyl ester. The condensation of malonic acid diethyl ether with acrylamide in phase transfer catalysis conditions leads to new derivative of malonic acid-1,1-dicarbethoxy-3-carbamoilpropane. The formation of mentioned compound has been followed by the method of UV spectrometry. The complexatation of the received substance investigated in relation to iron ions also.
Highlights
Synthesis of metal complex compounds of a number of vital elements based for instance as acetyl-carbethoxy-carbamoil containing group organic molecules is important task in chemistry, especially in metal-organic chemistry and chemical technology [1]
It has been mentioned that acrylamide enters Michael condensation with acetoacetic ether under Phase Transfer Catalytic (PTC) conditions “solid phase-liquid” [1]
In this article presents the results of studies on the synthesis of a polyfunctional substances as possible ligand based on with Malonic Acid Diethyl Ester (MADEE), where three atomic groups can functioned as donor atoms in the coordination complex
Summary
Synthesis of metal complex compounds of a number of vital elements based for instance as acetyl-carbethoxy-carbamoil containing group organic molecules is important task in chemistry, especially in metal-organic chemistry and chemical technology [1]. In this article presents the results of studies on the synthesis of a polyfunctional substances as possible ligand based on with Malonic Acid Diethyl Ester (MADEE), where three atomic groups can functioned as donor atoms in the coordination complex. In a flask equipped with a stirrer, reflux condenser and a dropping funnel at 20°C, a mixture of 9.12g (57.6mmol) of MADEE, 4.8ml of a 10N aqueous solution of KOH (57.6mmol) and 2.4mol of TMCACh were stirred.
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