Concurrent Superhydrophobicity and Thermal Energy Storage of Microcapsule with Superior Thermal Stability and Durability

Abstract

Despite considerable success in design and preparation of superhydrophobic particles, a facile and low-cost approach to develop multifunctional particles, especially microcapsules with the integrated performances of intrinsically long-lasting and highly stable superhydrophobicity and other passive/active functionalities, remains extremely challenging and is still in its infancy. Herein, we report a microcapsule (MC) with a micro/nano-hierarchical shell and a phase change material (PCM) core by a low-cost one-pot method. The resulting microcapsules (MCs) possess concurrent features of superhydrophobicity and thermal energy storage. Against thermal attack up to approximately 240 °C, the microstructure of MCs is nearly intact to avoid an obvious leakage of encapsulated PCM at high temperature, and meanwhile superhydrophobicity of MCs is enhanced unexpectedly to a static contact angle (CA) of 167.4 ± 0.3° and slide angle (SA) of 5 ± 0.5°. After conventional storage of 80 days, MCs still show a good superhydro...