Abstract
The interaction of CH 2I 2 and CH 2ICl with 60 fs laser pulses at 800 and 400 nm has been studied using TOF-MS. Molecular detachment of I 2 + and ClI + are observed. The generation of I 2 + and ClI + can be understood by a concerted elimination mechanism. The kinetic energy released is estimated from the peak splitting of I 2+ obtained in the TOF-MS, originated from Coulomb explosion. According to the results, multiphoton ionization is excluded from the possible mechanisms. The observed phenomena are attributed to the interaction of the intense laser field with the molecular potential energy surfaces.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.