Abstract
Abstract The analysis of the solubility of MSO 4 in the high-temperature cubic modification of Li 2 SO 4 reveals that divalent cations in the Li 2 SO 4 structure can occupy either tetrahedral or octahedral positions. The former case is preferred for Be 2+ , and, to some extent, for Zn 2+ . For all the other divalent cations the octahedral positions are prefered in the formation of the α-Li 2 SO 4 -based solid solutions.
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