Concentrations, sources and risks of PAHs in dissolved and suspended material particulate fractions from the Northwest Atlantic Coast of the Iberian Peninsula

Abstract

Anthropogenic activities can introduce polycyclic aromatic hydrocarbons (PAHs) in coastal waters. Here, 16 priority PAHs were quantified by gas chromatography-mass spectroscopy (GC–MS) in seawater samples from three Iberian Atlantic habitats. Results showed global concentrations of ≅9 ng/L in the aqueous phase (DAP) and ≅94 ng/g, dw in suspended particulate matter (SPM). The identified sources were both petrogenic and pyrogenic. Nonetheless, the application of several quantitative approaches, including Principal Component Analysis, point to distinct PAHs inputs amongst the sampling areas and demonstrate that sources in S1 (fire forests/sea harbor) are different from those at S2 and S3 (oil refinery/sea harbor). The calculated carcinogenicity potential in both DAP and SPM was low for humans (high percentage of Group 3 PAHs). However, both toxic equivalent factors (TEQs) and environmental risks coefficients (RQs) reveal that the evaluated areas are not risk-free, as confirmed by the practical Artemia salina acute-test assay.