Abstract
Earlier a general theory of solid surfaces was developed by one of us (MTCIP: Modern Thermodynamic Calculation of Interface Properties) [3, 5, 6]. A part of this theory describes the surface concentration profile for the thermodynamic equilibrium state by a system of non-linear equations. This system was solved in a first approximation for dilute mixtures and applied to several bimetallic alloys, with reliable results in several publications, even in the case of surface interactions with environmental (oxygen) atoms.
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