Concentration, Health Risk, and Hydrological Forcing of Heavy Metals in Surface Water Following Water-Sediment Regulation of the Xiaolangdi Dam in the Yellow River.

Abstract

Water and sediment regulation aimed at aquatic ecosystems and preserving reservoir capacity to minimize the negative consequences of dams can fundamentally change the distribution of heavy metals (HMs) in the reservoir and downstream reaches. However, the effects of water and sediment regulation on variation in HMs are still poorly understood. In this study, the variations in concentration, contamination, human health risk, potential sources, and influencing factors of the metalloid As and HMs (Cr, Hg, Ni, Pb, and Zn) in surface water in the reservoir and the downstream reach of the Xiaolangdi Dam (XLD) following the operation of the water-sediment regulation scheme (WSRS) were determined. These results indicate that HM concentrations in the two post-WSRS seasons were much lower than the water quality standards, but were significantly increased over time due to the trapping effects of the XLD (p < 0.05, except for Zn). However, As concentration in the reservoir was significantly lower than that observed in downstream reaches, likely due to anthropogenic input from agricultural activities. Meanwhile, HM concentrations varied with distance to the dam, which displayed a distinct accumulation closer to the dam in the post-WSRS II season. The contamination of HMs, the carcinogenic risk of exposure to As, and the noncarcinogenic risks associated with exposure to Hg, Ni, Pb, and Zn via the direct ingestion pathway of drinking water were all within acceptable levels following the WSRS, but increased over time. The carcinogenic risk of Cr in the post-WSRS II season was at an unacceptably high level, particularly at sites near the dam. Hydrological characteristics (water level and flow rate) were the dominant factors in determining the distribution of HMs. These results can provide new insight for a better understanding of the variations in HMs following the water and sediment regulation practices, and guide future management in regulating the trapping effects of dams.